Kk au2 - Fortified Fraternity

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Until now, phosphine, thiolate, and alkynyl-protected gold nanoclusters have been well identified based on total structure elucidations; however, it is still a challenge to acquire their X-ray quality single crystals and there are also many difficult questions still to be answered in this field, such as whether the face centered-cubic fcc structure in bulk gold would be preserved in these ultrasmall nanoclusters and how the organic ligands influence the configuration of the gold kernel, even for systems with the same nuclearity.